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Defended Dissertations in 2020


GIEDRIUS ABROMAVIČIUS
Author: GIEDRIUS ABROMAVIČIUS
Dissertation title: Microstructural and optical properties of metal oxide optical coatings deposited by ion beam sputtering and their application in UV spectral range
Fields of science: 
Material Engineering (T008)
Scientific supervisor: 
dr. Ramutis Drazdys
Defence of the dissertation:
February 25, 2020

SUMMARY:
Objective of the thesis was to extend the applicability of ion beam sputtered optical coatings for UV spectral range laser applications by optimizing plasma treatment of optical substrates, sputtering of material mixtures and post-deposition treatment of deposited coatings. Dissertation consists of introduction, literature overview, experimental methods, results and conclusions, list of references, summary and copies of author’s publications. Development of argon and oxygen plasma etching of fused silica substrates is presented, enabling realization of transparent optical components for high power UV lasers. Also, combined approach using HfO2-SiO2 mixtures and high temperature thermal annealing was demonstrated, enabling considerable increase of laser induced damage threshold and optical properties improvement of dielectric mirrors for 266 nm wavelength. Binary mixtures of common metal oxides - HfO2, Sc2O3 and Al2O3 were shown to be perspective candidates for development of stress compensated multilayer coatings for UV spectral range without degradation of optical, microstructural properties, if applying appropriate annealing temperature.
ROKAS ŽALNĖRAVIČIUS
Author: ROKAS ŽALNĖRAVIČIUS
Dissertation title: Synthesis, characterization and antimicrobial properties of metallic and semiconductor nanoparticles
Fields of science: 
Chemistry (N003)
Scientific supervisor: 
dr. Arūnas Jagminas
Defence of the dissertation: 
February 28, 2020

SUMMARY:
The main focus of this dissertation is on the cobalt ferrite nanoparticles (NPs), their size, core and composition-dependent influence on antimicrobial efficiency. In this study, the CoFe2O4 NPs were synthesized by hydrothermal, co-precipitation, thermal decomposition and electrochemical methods. The structure, composition and surface morphology were subsequently characterized by TEM, SEM, EDX, Raman, FTIR, ICP-OES, XRD techniques. Their antimicrobial activity was tested against well-known typical pathogens, which usually cause skin, tissue, blood and respiratory infections. For the first time, the dependency of antimicrobial properties of cobalt ferrite NPs on their size, chemical composition and shell has been shown. Furthermore, the antimicrobial activity of silver and copper oxide-based coatings, and ultra-small gold NPs was described in more detailed. It was determined that thin porous anodic aluminium oxide films with encapsulated metallic Ag nanowires, as thin as ≤ 1.0 μm, provide the antimicrobial, decorative and anticorrosive properties for food packing alumina foil. It has been shown for the first time, that ultra-small gold and magnetite-gold hybrid NPs exhibit the potential antimicrobial properties against multidrug resistant bacteria such as S. enterica, S. aureus MRSA and A. baumannii.
TADAS MATIJOŠIUS
Author: TADAS MATIJOŠIUS
Dissertation title: Tribological investigation of biocompatible nanostructured coatings and lubricating materials
Fields of science: 
Chemistry (N003)
Scientific supervisor: 
dr. Svajus Asadauskas
Defence of the dissertation: 
March 6, 2020

SUMMARY:
Bioceramic coatings of Al2O3 and Ti are used in medicine due to their inertness, biocompatibility and mechanical resistance. Al anodization is often used to obtain bioceramic Al2O3 coatings, but wear of anodized coatings remains one of the major problems. Several lipids were investigated to simulate friction in biological systems. Experiments showed that nanothin layers of Ti and its oxides significantly improve the biocompatibility and friction resistance of anodized coatings. Independently of the method (ALD or magnetron) used to form nanothin layers of Ti or its oxides, the layers of 10–75 nm thickness reduce COF below 0.2 retaining it 20 to 60 friction cycles. Nanothin layers of Zr and Hf oxides which belong to the group of IVB also reduce static friction, although they were less effective tribologically than Ti/TiO2. A novel method based on Raman spectroscopy has been developed to evaluate the penetration of hydrophilic azo compounds and hydrophobic compounds into the pores of the anodized foil. It has been found that the formation of tribofilms on the anodized coating takes place not only due to tribochemical reactions of the lubricants in the friction zone but also due to their chemical interaction with compounds present in the pores of anodized coating. In some cases their synergy reduces COF to ~0.1 and suppresses wear by more than 3 orders under dry friction conditions. Such dramatic wear reduction opens many new opportunities for anodized coatings.
AUŠRA BARADOKĖ
Author: AUŠRA BARADOKĖ
Dissertation title: Fabrication of miniaturised electrochemical sensor for cancerogenic biomarker detection
Fields of science: 
Chemistry (N003)
Scientific supervisor: 
prof. dr. Rasa Pauliukaite
Defence of the dissertation: 
May 29, 2020

SUMMARY:
In this dissertation simplification of sensor fabrication for carcinogenic metabolite H2O2 and biomarker carbohydrate antigen 125 sensing is demonstrated. The work explores combining of soft lithography and wet etching for rapid and simplified interdigitated microarray electrode fabrication and also achieving better sensor performance. Unique configuration of electrodes, where interdigitated microarrays are used as working and counter electrodes is explored. Such a configuration can change diffusion of redox active molecules from linear to spherical, which could potentially improve sensing performance. The sensor unique positioning of electrodes were studied by modelling expected electrochemical response using finite difference simulation method. Pt was electroplated at different scan rates controlling structure of Pt and roughness with high precision. This method allows performing the process without toxic agents (lead III), contrary to the established methods. The sensitivity for detection can be tuned by using more in depth data analysis methods for electrochemical impedance spectroscopy such as classical fitting to Randless equivalent circuit or imminence analysis, where components of resistance in impedance Z', Z'' vs frequency plots analysed at single frequencies giving faster data analysis. To improve sensing performance flat electrodes were modified by Au or Pt nanostructure and sensing performance for the first time between Au and Pt nanostructures compared. Nanostructured surface is expected to improve antibody loading, also different electroactivity properties between Au and Pt might lead to better values of sensing parameters such as slope and LOD. Fabricated electrodes can be used for electrochemical applications in biosensing.
DAINA UPSKUVIENĖ
Author: DAINA UPSKUVIENĖ
Dissertation title: Synthesis, characterization and investigation of properties of gold nanoparticles
Fields of science: 
Chemistry (N003)
Scientific supervisor: 
dr. Loreta Tamašauskaitė Tamašiūnaitė 
Defence of the dissertation:
September 4, 2020

SUMMARY:
Metal nanoparticles, especially gold nanoparticles (AuNPs) due to their optical, electronic, physicochemical, surface plasmon resonance properties, simple synthesis and functionalization are used in various fields of biomedicine, such as various sensor manufacturing, drug delivery, imaging, photothermal and photodynamic therapy. The properties of AuNPs or NPs of other metals are largely dependent on these nanostructured synthesis methods, so promising, cost-effective and efficient methods for synthesizing metal nanoparticles are being intensively sought to obtain nanostructures with high catalytic activity. The aim of the work – preparation of AuNPs, their characterization and application as anode materials in a direct glucose fuel cell. Simple and economical methods, such as reduction with citrate from an AuNPs colloidal solution, chemical adsorption, microwave synthesis, and galvanic displacement method have been used for the synthesis of AuNPs. Pure AuNPs and AuNPs supported carbon nanocomposites (AuNPs/C) have been synthesized using the chemical adsorption of AuNPs on the surface of carbon powder from a prepared citrate-stabilized AuNPs colloidal solution and microwave synthesis. AuNPs/C nanocomposites prepared by the both methods have been found to have significantly higher electrocatalytic activity for the oxidation of glucose in an alkaline medium compared with that of pure AuNPs catalyst. A method to modify the chemical adsorption synthesis by using halide additives (KCl, KBr, KI) has also been proposed for the preparation of catalysts that have AuNPs with different size and shape. It was found that the oxidation of glucose on those catalysts occurs at more negative electrode potential values, indicating a higher activity of them for glucose oxidation. Catalytically active substances for direct glucose fuel cells - AuNPs modified Co and CoB catalysts have been developed using electroless metal deposition and galvanic displacement methods.
VIDMANTAS JAŠINSKAS
Author: VIDMANTAS JAŠINSKAS
Dissertation title: Charge carrier generation and motion in single wall carbon nanotube/fullerene derivative films
Fields of science: 
Physics (N002)
Scientific supervisor: 
prof. habil. dr. Vidmantas Gulbinas 
Defence of the dissertation:
September 24, 2020

SUMMARY:
Much research has been done on single, separate carbon nanotubes (CNTs). Theoretical analysis of ongoing processes and explanation of experimentally measured data in such molecular systems are simpler and easier to implement. However, many practical applications require a bigger amount of material in one place. Analysis of physical processes, taking place in such layers of entangled CNTs, becomes more complicated, and thus the results are often controversial across different publications. Photovoltaic applications require a clear understanding of the photovoltaic processes in the materials, including exciton formation and charge carrier generation, as well as their subsequent dynamics. This dissertation aims to reveal photoelectric processes in CNT layers, formed from PFO Bpy copolymer-wrapped semiconducting (6,5) chirality single-wall carbon nanotubes (SWCNTs) and their blends with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM), in the broad timescale. This includes fast and ultrafast processes, starting with optical excitation induced exciton formation, free charge carrier separation, and following their migration and recombination. The time interval, examined in the dissertation, also includes particularly slow processes, such as the formation and decay of long-lasting built-in electric field, induced by an external electric field.
ELENA LAGZDINA
Author: ELENA LAGZDINA
Dissertation title: Radiological and structural characterization of RBMK-1500 reactor graphite and application of the ion implantation method to investigate irradiation damage in graphite
Fields of science: 
Physics (N002)
Scientific supervisor: 
dr. Rita Plukienė
Defence of the dissertation: 
September 28, 2020

SUMMARY:
Graphite is widely used as a moderator, reflector, and fuel matrix in various types of nuclear reactors. Over 250,000 tons of irradiated graphite is temporarily stored in interim storage facilities at nuclear power plants worldwide and each country decides individually how to handle this waste. The total mass of graphite at Ignalina Nuclear Power Plant (INPP) in Lithuania is ~3 820 tons. Graphite as a major structural component material of the RBMK-1500 nuclear reactor core is subjected to high levels of radiation, which affects both physical and chemical properties of material. In order to optimize the disposal strategy of the irradiated graphite waste, the radiological and structural characterization of graphite is needed. In this work, the concentrations of the several impurities in different types of the RBMK-1500 reactor graphite (stack (GR-280), bushing and sleeve (GRP-2-125)) are determined for the first time. Moreover, the rapid analysis method for the experimental determination of specific 14C activity in irradiated graphite is proposed and applied. The radiological and structural characterization of RBMK-1500 reactor graphite is carried out both experimentally and theoretically. Based on the reactor operational conditions the ion implantation method is applied and the new data about structural properties of the RBMK-1500 reactor graphite are presented. The complex analysis of the 14C activity distribution in the irradiated RBMK-1500 reactor graphite is provided.
MARTYNAS ŠAPUROV

Author: MARTYNAS ŠAPUROV
Dissertation title: Development of Smooth Asymmetric Reactive Power Compensator
Fields of science: Electrical and Electronics Engineering (T001)
Scientific supervisor: dr. Algirdas Baškys
Defence of the dissertation: September 28, 2020

SUMMARY:
The aim of the performed research is development of reactive power compensators for the smooth and asymmetric reactive power compensation in the low voltage utility grid. The cascaded inverter has been modified and adapted for the smooth compensation of reactive power. The topologies of the conventional and cascaded inverter-based reactive power compensators with the individual inverters for the every phase for the asymmetric compensation of reactive power have been proposed. The shunt-connected compensator for the smooth and asymmetric compensation of reactive power in the low voltage utility grid has been developed. The investigation of developed reactive power compensators was performed using simulation and experimentally. The dissertation consists of an introduction, three chapters, general conclusions, references and the list of author's publications on the topic of the dissertation. The research problem, the relevance of the work, the object of research are presented in the introductory chapter. The aim and objectives of the work, the research methodology, scientific novelty of the work, the practical significance of the work results, defended statements are presented as well. At the end of the introduction, the author's publications and conference papers on the topic of the dissertation and the structure of the dissertation are given. The first chapter analyzes the reactive power compensation techniques and compensator types. The inverter-based reactive power compensators and shuntconnected reactive power compensators are analyzed. The conclusions are drawn out and the tasks of the dissertation are formulated. The conventional and cascaded inverter-based reactive power compensators are analyzed in the second chapter. The topologies of reactive power compensators with the individual ordinary inverters and cascaded inverters for the every phase for the asymmetric compensation of reactive power are proposed. The Matlab/Simulink models of compensators were created and investigation of compensators using simulation was performed. In the third chapter the developed shunt-connected compensator for smooth asymmetric compensation of reactive power in low voltage utility grid is presented. The investigation of compensator was performed experimentally using developed experimental test bench. The main results of the dissertation have been published in 4 scientific publications – 3 of them have been published in peer-reviewed scientific journals, 1 in conference proceedings. The results were presented at 5 scientific conferences.

EDVARDAS BIELSKIS

Author: EDVARDAS BIELSKIS
Dissertation title: Development of energy efficient photovoltaic microinverter
Fields of science: Electrical and Electronics Engineering (T001)
Scientific supervisor: dr. Algirdas Baškys
Defence of the dissertation: September 28, 2020

SUMMARY:
The aim of the performed research is to improve the efficiency of the photovoltaic grid tied microinverter and reduce the nonlinear distortions of the microinverter current supplied to the electricity network. An energy-efficient single-stage photovoltaic microinverter has been developed and investigated. The control algorithm and the controller has been developed for the tracking of sinus shape of the microinverter output current. The investigation was performed using simulation and experimentally. The dissertation consists of an introduction, three chapters, general conclusions, references and the list of author's publications on the topic of the dissertation. The research problem, the relevance of the work, the object of research are presented in the introductory chapter. The aim and objectives of the work, the research methodology, scientific novelty of the work, the practical significance of the work results, defended statements are presented as well. At the end of the introduction, the author's publications and conference papers on the topic of the dissertation and the structure of the dissertation are given. In the first chapter, the research analysis of the properties of photovoltaic inverters is performed. The principles of operation of photovoltaic microinverters are analyzed, their advantages and disadvantages are discussed, microinverter output current control systems are analyzed. DC-DC (DC – direct current) voltage converters used in microinverters are reviewed. The tasks of the dissertation are formulated. The experimental investigation results of efficiency of a developed DC-DC voltage flyback converter with an alternative active surge suppression circuit and a two-switch DC-DC flyback converter are presented in the second chapter. A new single stage grid tied photovoltaic microinverter based on couple of two-switch DC-DC flyback converters has been proposed. The investigation of proposed microinverter efficiency was performed. In the third chapter a new PI controller with a time-varying proportional constant is proposed and a microinverter output current sinus shape tracking system with a developed controller was investigated. The nonlinear distortions of the current were evaluated. The influence of parameters of the microinverter elements on the microinverter efficiency was investigated. The flyback transformer used in the microinverter has been upgraded. The main results of the dissertation have been published in 7 scientific publications – 5 of them have been published in peer-reviewed scientific journals, 2 in conference proceedings. The results were presented at 10 scientific conferences.

MAŽENA MACKOIT-SINKEVIČIENĖ
Author: MAŽENA MACKOIT-SINKEVIČIENĖ
Dissertation title: Point defects as single-photon emitters in hexagonal boron nitride: theoretical study
Fields of science: 
Physics (N002)
Scientific supervisor: 
prof. dr. Audrius Alkauskas
Defence of the dissertation: 
October 19, 2020

SUMMARY:
Future light-based quantum technologies will depend on generation and manipulation of single photons, thus any quantum device will contain one crucial component within – single-photon emitter. So far, among the frontrunners are solid-state single-photon emitters, and they are expected to play an essential role in a plethora of quantum tasks. The recent discovery that hexagonal boron nitride can host robust, narrow-linewidth, bright, photostable, and indistinguishable single-photon sources operating at room temperature and above has sparked interest in this material. This Thesis synthesizes the results of theoretical work on the understanding the role of point defects in hexagonal boron nitride, in particular for the observed single-photon emission, by performing first-principles calculations. A significant step forward in the study was provided by giving a broad and comprehensive picture of the defect chemistry in hexagonal boron nitride. The author of this Thesis ensured a correct treatment of defect physics, and thereby illustrated ability to predict and assign microscopic identity of single-photon emitters in hexagonal boron nitride on scales unreachable for the experiment, using a purely first-principles approach. Physical model for quenching of 2 eV single-photon emission in this material was proposed. The author of this Thesis unpretentiously believes that the study covered in the last chapter of Thesis has also made its small contribution towards a more in-depth understanding of ultraviolet single-photon emission in hexagonal boron nitride by giving convincing explanations for obtained results.
JULIJA PAURAITĖ-DUDEK
Author: JULIJA PAURAITĖ-DUDEK
Dissertation title: The impact of submicron aerosol source and physical-chemical parameters on atmospheric radiative balance
Fields of science: 
Physics (N002)
Scientific supervisor: 
dr. Vidmantas Ulevičius 
Defence of the dissertation: 
November 20, 2020

SUMMARY:
Aerosols due to their ability to scatter and absorb light play a significant role in climate radiative budged. The largest uncertainty of the Earth’s climate system radiative forcing assessment are assigned to aerosols and clouds. This uncertainty is a result of complex chemical and physical processes in the atmosphere, which remain not fully understood to this day. In order to investigate aerosols impact on climate it is crucial to broaden the understanding of black carbon and brown carbon sources, their aging and oxygenating processes together with their impact on atmospheric radiative budged. This thesis consists of identification of main sources of organic aerosol, assessment of aerosol main physical and chemical properties and their importance to the atmospheric radiative balance. The first part of the thesis is a literature review. The description of used instrumentation and methods are presented in the second part. The third part consists of results: identification of main sources of organic aerosol in urban, rural and marine environments, assessment of the impact of different aerosol sources and parameters on single scattering albedo and evaluation of the importance of fog, smog and grass burning events for atmospheric radiative balance.
VYTAUTAS JANONIS
Author: VYTAUTAS JANONIS
Dissertation title: Development of terahertz diffractive optics and plasmon-phonon polaritonics components
Fields of science: 
Material Engineering (T008)
Scientific supervisor: 
dr. Irmantas Kašalynas
Defence of the dissertation: 
November 20, 2020

SUMMARY:
In this dissertation two main topics are discussed, relevant to the development of modern, compact and widespread application spectroscopic terahertz imaging systems. Namely development of terahertz diffractive optics and variable frequency polaritonic infrared optical components is described. Development and performance of direct laser ablation fabricated multilevel phase Fresnel lenses and metal Soret zone plates for focusing of 0.6 and 4.7 THz frequency radiation are discussed in the first part of this dissertation. Characterization of fabricated components was carried out, demonstrating the applicability of the fabrication method in component development. Optimal lens design was also found and application of a fabricated component in an experimental 0.6 THz frequency imaging setup was demonstrated. Second part of this dissertation deals with the development of polaritonic components with specifically designed infrared spectral features in the infrared spectral range described by the Reststrahlen band of the semiconductor. Optical spectra modelling of heavily doped n-GaN surface relief gratings and metal grating coupled heterostructures was carried out using custom modified rigorous coupled wave analysis method. Optimal n-GaN grating height and periodicity were chosen and fabrication was carried out according to the optimal modelled parameters. Close match was demonstrated between the modelled and experimental results therefore validating the modeling and fabrication methods in developing optical components with custom frequency spectral features. Finally, it was shown that thermally excited n-GaN surface relief gratings are applicable in developing coherent, variable frequency infrared thermal sources.
AGNĖ MIKALAUSKAITĖ

Author: AGNĖ MIKALAUSKAITĖ
Dissertation title: Investigation on the surface decoration of magnetic iron oxide nanoparticles with gold nanocomposites
Fields of science: 
Chemistry (N003)
Scientific supervisor: 
dr. Arūnas Jagminas
Defence of the dissertation: 
November 27, 2020

SUMMARY:
A simple method for coating the surface of magnetic Nps with gold using vitamin C as a reducing agent capable of to binding with cobalt ferrite was developed. This study describes a novel and efficient way for covering of various cobalt ferrite nanoparticles with gold shell without nucleation and growth of the separate gold crystals using methionine as a reducer of gold species and stabilizing agent of Nps. Formation of CoFe2O4@Au NPs was confirmed by XRD, TEM, EDX, high-resolution TEM studies, variation of NPs size, and FTIR spectra. FTIR spectral analysis showed different adsorption behavior of dopamine hydrochloride on the surface of CoFe2O4 and CoFe2O4 @ Au NPs. Gold cluster synthesis for the first time using a branched-chain amino acid food supplement was optimized. The obtained gold clusters characterized by intense red photoluminescence, peaked in a vicinity of 670–710 nm, a relatively long lifetime of several microseconds, and high quantum yield of approximately 7%, similar to ones synthesized with bovine serum albumin.

Doctoral dissertation

AUDRIUS DRABAVIČIUS

Author: AUDRIUS DRABAVIČIUS
Dissertation title: Formation of chalcogenide solar cell absorber layers using electrochemical deposition of precursors
Fields of science: 
Chemistry (N003)
Scientific supervisor: 
habil. dr. Remigijus Juškėnas
Defence of the dissertation: 
November 27, 2020

SUMMARY:
The main focus of this dissertation is on the copper-zinc-tin sulfide thin films, their synthesis, and research. Thin films formed by sulfurizing/selenizing electrochemically deposited Cu-Sn and Cu-Sn-Zn precursor layers were investigated in the work. Different methods of electrochemical deposition of the precursor were tested and compared, including the electrochemical deposition of metals using a unique electrochemical cell produced by a 3D printer. Also, the conditions of sulfurization/selenization of the precursor layers were investigated. The phase composition and photoelectrochemical activity of the formed CTSe layers were investigated. The formed CZTS absorber layers were characterized using SEM, TEM, EDX, Raman spectroscopy, photoelectrochemical analysis, XRD, and photoluminescence analysis methods. Significant attention in the dissertation was given to determine the phase composition and the defects formed in the kesterite layer. For the first time, electrochemically formed CZTS layers were investigated by the XRD method using Cu Kα1 radiation. The kesterite crystalline structure order/disorder levels determined by Raman spectroscopy and by RSD methods were compared.

DOMAS JOKUBAUSKIS

Author: DOMAS JOKUBAUSKIS
Dissertation title: Development and applications of compact spectroscopic terahertz imaging systems using principles of optical beam engineering
Fields of science: 
Physics (N002)
Scientific supervisor: 
prof. habil. dr. Gintaras Valušis
Defence of the dissertation:
December 10, 2020

SUMMARY:
The dissertation objective was to investigate and improve terahertz (THz) imaging techniques allowing for inspection of hidden objects without harmful X-rays. The work was carried out as follows. Firstly, an efficient and cost-effective compact homodyne THz imaging scheme was developed using reliable bow-tie diodes as an alternative to heterodyne THz imaging technique for low absorbing object identification using paper sheets for phase shifting at 0.3 THz and 0.6 THz frequencies. Secondly, effect of molecular beam epitaxy growth conditions on InGaAs/InP layers dedicated for bow-tie diodes fabrication was investigated and optimal growth regime with respect to InGaAs diodes parameters was determined. Furthermore, silicon diffractive optics-based Fibonacci bifocal THz lens was designed, fabricated and investigated. Additionally, the designed bifocal THz lens was applied for THz imaging, demonstrating simultaneous multi-focal THz imaging. Moreover, diffractive THz lens allowing Bessel THz imaging was developed with extended focal depth up to 20 mm suitable for imaging of objects hidden in post packages. Additionally, purely silicon optics based Bessel THz imaging was demonstrated and deconvolution algorithms were applied for enhancement of the contrast. Finally, THz beam manipulation using spatial filtering methods was investigated and applied for THz imaging revealing its advantages in comparison with other beam engineering methods.

ROKAS NAUJALIS

Author: ROKAS NAUJALIS
Dissertation title: Star Clusters in Galaxies. Multicolour HST photometry
Fields of science: 
Physics (N002)
Scientific supervisor: 
prof. dr. Vladas Vansevičius
Defence of the dissertation: 
December 11, 2020

SUMMARY:
Star clusters are composed of stars with similar age and chemical composition. This makes them a powerful tool for studying star formation histories of galaxies. We studied star clusters in two types of galaxies. So far, only one cluster has been known in the irregular dwarf galaxy Leo A, and we have discovered four more low-mass young clusters. In the Andromeda galaxy, cluster aperture photometry is strongly affected by the large number of bright field stars. To reduce their influence, we have developed a new method of adaptive aperture photometry. Using it, we performed aperture photometry of 1181 clusters on CCD mosaics taken from the Hubble Space Telescope archive and demonstrated that our results are more consistent with theoretical models than previously published data. We also modeled the collapse of molecular clouds at different ambient pressures and showed that in high-pressure environments, the efficiency of star formation is higher and newly formed clusters are more strongly bound by gravity.

MONIKA KIRSNYTĖ

Author: MONIKA KIRSNYTĖ
Dissertation title: Semiconductor polymeric composites formation by bioinspired in situ polymerization process with non-conductive substrates
Fields of science: 
Chemistry (N003)
Scientific supervisor: 
dr. Arūnas Stirkė
Defence of the dissertation: 
December 11, 2020

SUMMARY:
In recent decades, polymers have been extensively studied for their specific tunable intrinsic electrical conductivity properties and various application possibilities in radar-absorbent materials, smart textiles, flexible electronics, biosensors or energy harvesting, or energy-storing materials. Therefore, there is a need to produce and investigate various semiconductive composites. This thesis presents semiconductor composites of polymer origin by bioinspired in situ polymerization process by utilizing non-conductive substrates. Firstly, a new biogenic polypyrrole (PPy) microsphere synthesis method with Streptomyces spp. bacteria were applied and analysed. We tried to mimic the polymerization, as mentioned earlier, results by a bioinspired microemulsion polymerization process in microfluidic systems. Also, we implement a novel PPy in situ polymerization process on non-conductive surfaces, including various textiles, which leads to conductive composite formation. Composites dopant incorporation into an adhesive matrix or pyrrole aqueous solution results in dependencies for electrical conductivity and shielding effectiveness parameters to evaluate PPy composites efficiency for electromagnetic wave absorbent materials.

JONAS KLIMANTAVIČIUS

Author: JONAS KLIMANTAVIČIUS
Dissertation title: Semiconductor polymeric composites formation by bioinspired in situ polymerization process with non-conductive substrates
Fields of science: 
Material Engineering (T008)
Scientific supervisor: 
prof. habil. dr. Nerija Žurauskienė
Defence of the dissertation: 
December 18, 2020

SUMMARY:
The magnetoresistive properties of lanthanum manganites are attracting considerable interest of research and applications. It was demonstrated that manganite La1-xSrxMnO3 (LSMO) films exhibiting colossal magnetoresistance (CMR) effect can be successfully used for the development of CMR-B-scalar sensors operating at room temperatures and measuring the absolute magnitude of magnetic flux density in very small volumes. This thesis is focused on the investigation of magnetoresistive properties of the LSMO films to use them for pulsed magnetic field measurements at room and higher temperatures. The study presents the investigation of LSMO films grown on glass ceramics by pulsed injection MOCVD method, and demonstrates possibility to tune their magnetoresistive properties in a wide range of temperatures and magnetic fields by changing film thickness and deposition temperature. Further, it is shown that Mn excess in LSMO films could significantly increase their metal-insulator transition temperature and thus increase the magnetoresistance values at higher than room temperatures. Also, the dependence of the magnetoresistive properties of the LSMO films grown on different substrates (AT-cut quartz, Al2O3 and Si/SiO2-1000) is investigated and analyzed in the thesis. Finally, the successful application of CMR-B-scalar sensors, produced using LSMO films with Mn excess on Al2O3 substrate, for the investigation of magnetic field dynamics during Magnetic Pulse Welding (MPW) of metals is presented. The possibility to use these sensors for the analysis of MPW processes and nondestructive evaluation of welding quality is demonstrated.