Structure

Perovskite solar cells and light-emitting diodes

Principal Investigators: 

  • Dr. Marius Franckevičius 
  • dokt. Rokas Gegevičius 
Lead halide perovskites are currently considered as one the most promising materials for novel, thin-film solar cells. These cells are made using cheap materials and technologies, and their efficiency currently exceeds 25%, which is close to the efficiency of conventional inorganic Si-based devices. Therefore, they are very attractive candidates to replace inorganic solar cells and hold great promise for stimulating a breakthrough in the development of renewable energetics. Metalorganic perovskites are also perspective materials for other optoelectrical devices, such as light-emitting diodes or photodetectors. However, despite the spectacular advance during recent years in increasing the performance of the perovskite-based optoelectronic devices, their long-term stability and lead toxicity are the main crucial problems obstructing their practical applications. To improve the stability of perovskite solar cells and replace toxic materials with environmentally friendly ones, our primary goal is to understand the fundamental processes limiting the performance of the solar cells and light-emitting diodes, and then find the possible ways to improve the material quality.


Funding
R&D project “Stability of perovskite solar cells: identification and control of degradation processes". NR.09.3.3-LMT-K-712-01-0031. 2018-2021. Value 599 983 Eur.
Selected publications
  1. R. Gegevičius, M. Franckevičius, J. Chmeliov, W. Tress, V. Gulbinas. Electroluminescence Dynamics in Perovskite Solar Cells Reveals Giant Overshoot EffectThe Journal of Physical Chemistry Letters, 2019, 10, 1779-1783.
  2. R. Gegevičius, M. Treideris, V. Pakštas, M. Franckevičius, V. Gulbinas. Oxide Layer Enhances Photocurrent Gain of the Planar MAPbI3 PhotodetectorAdvanced Electronic Materials, 2018, 4, 1800114.
  3. N. Marinova, M. Franckevičius, I. Matulaitienė, A. Devižis, G. Niaura, V. Gulbinas, J.L. Delgado. Hindered Amine Light Stabilizers Increase the Stability of Methylammonium Lead Iodide Perovskite Against Light and OxygenChemSusChem, 2017, 10, 3760–3764.
  4. R. Augulis, M. Franckevičius, V. Abramavičius, D. Abramavičius, S. M. Zakeeruddin, M. Grätzel, V. Gulbinas. Multistep Photoluminescence Decay Reveals Dissociation of Geminate Charge Pairs in Organolead Trihalide Perovskites.Advanced Energy Materials, 2017, 7, 1700405.
  5. M. Franckevičius, A. Mishra, F. Kreuzer, J. Luo, S.M. Zakeeruddin, and M. Grätzel. A dopant-free spirobi[cyclopenta[2,1-b:3,4-b′]dithiophene] based hole-transport material for efficient perovskite solar cellsMaterials Horizons, 2015, 2, 613.